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51.
与角岩有关的矿床主要类型及其对深部找矿的意义   总被引:2,自引:0,他引:2  
作为热接触变质的产物,角岩在石墨、硅灰石、红柱石等变质成因非金属矿床和各种金属矿床以及油气矿藏均可见,但对其调查研究成果并不多。在文献综述的基础上,结合在南岭、冈底斯等重要成矿带地质找矿的实践,通过对与矿产资源有关的角岩广义概念的界定,概述了与角岩有关的各主要类型矿床的地质特征,如石墨、硅灰石、红柱石等变质成因非金属矿床,钨、钼、铁、铜、铀、金、铅锌、锡、银和稀有金属矿床以及油气矿藏;举例阐述了近年来角岩发育矿区深部找矿中的新突破,如江西淘锡坑钨矿,广西大厂铜坑至拉么一带的锡多金属矿床,西藏甲玛铜多金属矿,云南老厂银铅锌矿、羊拉铜矿、雪鸡坪铜矿等矿区;讨论了角岩型矿床成矿预测的准则。结果表明:矿区和矿田大比例尺深部预测时应注意岩石组合、干湿关系、封闭与开放体系、岩石物性和分带性、原岩岩性及其空间配置关系;区域性中、小比例尺成矿评价时应注意角岩的空间分布、岩石学特征与矿产资源的专属性关系等;利用角岩预测隐伏岩体的应用前景广泛,在深部找矿中具有现实意义。建议加强角岩与成矿关系的理论研究,对以往地质填图工作中发现的"角岩化带"可重新评价其与成矿的关系。  相似文献   
52.
Kyanite‐ and phengite‐bearing eclogites have better potential to constrain the peak metamorphic P–T conditions from phase equilibria between garnet + omphacite + kyanite + phengite + quartz/coesite than common, mostly bimineralic (garnet + omphacite) eclogites, as exemplified by this study. Textural relationships, conventional geothermobarometry and thermodynamic modelling have been used to constrain the metamorphic evolution of the Tromsdalstind eclogite from the Tromsø Nappe, one of the biggest exposures of eclogite in the Scandinavian Caledonides. The phase relationships demonstrate that the rock progressively dehydrated, resulting in breakdown of amphibole and zoisite at increasing pressure. The peak‐pressure mineral assemblage was garnet + omphacite + kyanite + phengite + coesite, inferred from polycrystalline quartz included in radially fractured omphacite. This omphacite, with up to 37 mol.% of jadeite and 3% of the Ca‐Eskola component, contains oriented rods of silica composition. Garnet shows higher grossular (XGrs = 0.25–0.29), but lower pyrope‐content (XPrp = 0. 37–0.39) in the core than the rim, while phengite contains up to 3.5 Si pfu. The compositional isopleths for garnet core, phengite and omphacite constrain the P–T conditions to 3.2–3.5 GPa and 720–800 °C, in good agreement with the results obtained from conventional geothermobarometry (3.2–3.5 GPa & 730–780 °C). Peak‐pressure assemblage is variably overprinted by symplectites of diopside + plagioclase after omphacite, biotite and plagioclase after phengite, and sapphirine + spinel + corundum + plagioclase after kyanite. Exhumation from ultrahigh‐pressure (UHP) conditions to 1.3–1.5 GPa at 740–770 °C is constrained by the garnet rim (XCaGrt = 0.18–0.21) and symplectite clinopyroxene (XNaCpx = 0.13–0.21), and to 0.5–0.7 GPa at 700–800 °C by sapphirine (XMg = 0.86–0.87) and spinel (XMg = 0.60–0.62) compositional isopleths. UHP metamorphism in the Tromsø Nappe is more widespread than previously known. Available data suggest that UHP eclogites were uplifted to lower crustal levels rapidly, within a short time interval (452–449 Ma) prior to the Scandian collision between Laurentia and Baltica. The Tromsø Nappe as the highest tectonic unit of the North Norwegian Caledonides is considered to be of Laurentian origin and UHP metamorphism could have resulted from subduction along the Laurentian continental margin. An alternative is that the Tromsø Nappe belonged to a continental margin of Baltica, which had already been subducted before the terminal Scandian collision, and was emplaced as an out‐of‐sequence thrust during the Scandian lateral transport of nappes.  相似文献   
53.
Eclogites from the Kebuerte Valley, Chinese South Tianshan, consist of garnet, omphacite, phengite, paragonite, glaucophane, hornblendic amphibole, epidote, quartz and accessory rutile, titanite, apatite and carbonate minerals with occasional presence of coesite or quartz pseudomorphs after coesite. The eclogites are grouped into two: type I contains porphyroblastic garnet, epidote, paragonite and glaucophane in a matrix dominated by omphacite where the proportion of omphacite and garnet is >50 vol.%; and type II contains porphyroblastic epidote in a matrix consisting mainly of fine‐grained garnet, omphacite and glaucophane where the proportion of omphacite and garnet is <50 vol.%. Garnet in both types of eclogites mostly exhibits core–rim zoning with increasing grossular (Xgr) and pyrope (Xpy) contents, but a few porphyroblastic garnet grains in type I eclogite shows core–mantle zoning with increasing Xpy and a slight decrease in Xgr, and mantle–rim zoning with increases in both Xgr and Xpy. Garnet rims in type I eclogite have higher Xpy than in type II. Petrographic observations and phase equilibria modelling with pseudosections calculated using thermocalc in the NCKMnFMASHO system for three representative samples suggest that the eclogites have experienced four stages of metamorphism: stage I is the pre‐peak temperature prograde heating to the pressure peak (Pmax) which was recognized by the garnet core–mantle zoning with increasing Xpy and decreasing Xgr. The PT conditions at Pmax constrained from garnet mantle or core compositions with minimum Xgr content are 29–30 kbar at 526–540 °C for type I and 28.2 kbar at 518 °C for type II, suggesting an apparent thermal gradient of ~5.5 °C km?1. Stage II is the post‐Pmax decompression and heating to the temperature peak (Tmax), which was modelled from the garnet zoning with increasing Xgr and Xpy contents. The PT conditions at Tmax, defined using the garnet rim compositions with maximum Xpy content and the Si content in phengite, are 24–27 kbar at 590 °C for type I and 22 kbar at 540 °C for type II. Stage III is the post‐Tmax isothermal decompression characterized by the decomposition of lawsonite, which may have resulted in the release of a large amount of fluid bound in the rocks, leading to the formation of epidote, paragonite and glaucophane porphyroblasts. Stage IV is the late retrograde evolution characterized by the overprint of hornblendic amphibole in eclogite and the occurrence of epidote–amphibole facies mineral assemblages in the margins or in the strongly foliated domains of eclogite blocks due to fluid infiltration. The PT estimates obtained from conventional garnet–clinopyroxene–phengite thermobarometry for the Tianshan eclogites are roughly consistent with the P–T conditions of stage II at Tmax, but with large uncertainties in temperature. On the basis of these metamorphic stages or P–T paths, we reinterpreted that the recently reported zircon U–Pb ages for eclogite may date the Tmax stage or the later decompression stage, and the widely distributed (rutile‐bearing) quartz veins in the eclogite terrane may have originated from the lawsonite decomposition during the decompression stage rather than from the transition from blueschist to eclogite as previously proposed.  相似文献   
54.
Centimetre‐ to decimetre‐wide quartz+calcite veins in schistes lustrés from Alpine Corsica were formed during exhumation at 30–40 Ma following blueschist facies metamorphism. The δ18O and δ13C values of the veins overlap those of the host schistes lustrés, and the δ18O values of the veins are much higher than those of other rocks on Corsica. These data suggest that the vein‐forming fluids were derived from the schistes lustrés. Fluids were probably generated by reactions that broke down carpholite, lawsonite, chlorite and white mica at 300–350 °C during decompression between c. 1400 and 800 MPa. However, the δ18O values of the veins are locally several per mil higher than expected given those of their host rocks. The magnitude of oxygen isotope disequilibrium between the veins and the host rock is inversely proportional to the δ18O value of the host rock. Additionally, calcite in some schists is in isotopic equilibrium with calcite in adjacent veins, but not with the silicate fraction of the schists. Locally, the schists are calcite bearing only within 1–20 cm of the veins. The vein‐forming fluids may have been preferentially derived from calcite‐bearing, high‐δ18O rocks that are common within the schistes lustrés and that locally contain abundant (>15%) veins. If the fluids were unable to completely isotopically equilibrate with the rocks, due to relatively rapid flow at moderate temperatures or being confined to fractures, they could form veins with higher δ18O values than those of the surrounding rocks. Alteration of the host rocks was probably inhibited by isolation of the fluid in ‘quartz‐armoured’ veins. Overall, the veins represent a metre‐ to hectometre‐scale fluid‐flow system confined to within the schistes lustrés unit, with little input from external sources. This fluid‐flow system is one of several that operated in the western Alps during exhumation following high‐pressure metamorphism.  相似文献   
55.
Progressive Early Silurian low‐pressure greenschist to granulite facies regional metamorphism of Ordovician flysch at Cooma, southeastern Australia, had different effects on detrital zircon and monazite and their U–Pb isotopic systems. Monazite began to dissolve at lower amphibolite facies, virtually disappearing by upper amphibolite facies, above which it began to regrow, becoming most coarsely grained in migmatite leucosome and the anatectic Cooma Granodiorite. Detrital monazite U–Pb ages survived through mid‐amphibolite facies, but not to higher grade. Monazite in the migmatite and granodiorite records only metamorphism and granite genesis at 432.8 ± 3.5 Ma. Detrital zircon was unaffected by metamorphism until the inception of partial melting, when platelets of new zircon precipitated in preferred orientations on the surface of the grains. These amalgamated to wholly enclose the grains in new growth, characterised by the development of {211} crystal faces, in the migmatite and granodiorite. New growth, although maximum in the leucosome, was best dated in the granodiorite at 435.2 ± 6.3 Ma. The combined best estimate for the age of metamorphism and granite genesis is 433.4 ± 3.1 Ma. Detrital zircon U–Pb ages were preserved unmodified throughout metamorphism and magma genesis and indicate derivation of the Cooma Granodiorite from Lower Palaeozoic source rocks with the same protolith as the Ordovician sediments, not Precambrian basement. Cooling of the metamorphic complex was relatively slow (average ~12°C/106y from ~730 to ~170°C), more consistent with the unroofing of a regional thermal high than cooling of an igneous intrusion. The ages of detrital zircon and monazite from the Ordovician flysch (dominantly composite populations 600–500 Ma and 1.2–0.9 Ga old) indicate its derivation from a source remote from the Australian craton.  相似文献   
56.
U–Pb isotopic data from the northern Monashee complex, one of the deepest structural exposures in the southern Canadian Cordillera, indicate that the age of metamorphism varies according to structural position in a 6 km thick section. This metamorphism resulted in an unusual sequence in which rocks with the lowest-grade mineral assemblage (kyanite–sillimanite–staurolite–muscovite) are underlain and overlain by higher-grade rocks. Xenotime and monazite U–Pb dates vary progressively from 64 Ma in the structurally highest rocks to 49 Ma in the deepest rocks. Discordant U–Pb ages from Proterozoic and Cretaceous monazite and titanite are used to interpret the thermal significance of the early Tertiary dates. The discordant analyses define linear arrays with lower intercepts that broadly overlap with early Tertiary, and the amount of discordance varies with structural level; it is least in the deeper rocks and greatest in higher rocks. Electron microprobe work showed that the monazite discordance in the deeper rocks resulted from Tertiary mineral overgrowth and recrystallization rather than Pb diffusion. We use previous studies of Pb diffusion and the fact that Proterozoic monazite and titanite suffered only negligible to moderate amounts of diffusive Pb loss to contend that elevated temperatures (c. 600–650 °C are inferred from pelitic mineral assemblages) existed in the deeper rocks for a short duration, perhaps a few million years. The downwards younging 64–49 Ma U–Pb dates are interpreted as closely reflecting xenotime and monazite growth ages rather than cooling ages or substantially reset ages based on the lack of Pb diffusion in monazite and the previously obtained 40Ar/39Ar data which suggest that rapid cooling occurred immediately after the U–Pb dates. In addition, growth ages are interpreted as thermal peak ages based on U–Pb dates from coeval kyanite-bearing leucosomes, the consistent nature of the U–Pb dates throughout the study area, and petrographic relationships which suggest that monazite grew before or during development of the syn-metamorphic foliation. These interpretations lead us to conclude that metamorphism was diachronous according to structural level, with higher rocks attaining peak temperatures and cooling rapidly while deeper rocks were heating towards a thermal peak that was attained a few million years later. This thermal scenario requires that higher rocks cannot have been the heat source for the deeper metamorphism, as was previously proposed.  相似文献   
57.
The eclogite facies assemblage K-feldspar–jadeite–quartz in metagranites and metapelites from the Sesia-Lanzo Zone (Western Alps, Italy) records the equilibration pressure by dilution of the reaction jadeite+quartz=albite. The metapelites show partial transformation from a pre-Alpine assemblage of garnet (Alm63Prp26Grs10)–K-feldspar–plagioclase–biotite±sillimanite to the Eo-Alpine high-pressure assemblage garnet (Alm50Prp14Grs35)–jadeite (Jd80–97Di0–4Hd0–8Acm0–7)–zoisite–phengite. Plagioclase is replaced by jadeite–zoisite–kyanite–K-feldspar–quartz, and biotite is replaced by garnet–phengite or omphacite–kyanite–phengite. Equilibrium was attained only in local domains in the metapelites and therefore the K-feldspar–jadeite–quartz (KJQ) barometer was applied only to the plagioclase pseudomorphs and K-feldspar domains. The albite content of K-feldspar ranges from 4 to 11 mol% in less equilibrated assemblages from Val Savenca and from 4 to 7 mol% in the partially equilibrated samples from Monte Mucrone and the equilibrated samples from Montestrutto and Tavagnasco. Thermodynamic calculations on the stability of the assemblage K-feldspar–jadeite–quartz using available mixing data for K-feldspar and pyroxene indicate pressures of 15–21 kbar (±1.6–1.9 kbar) at 550±50 °C. This barometer yields direct pressure estimates in high-pressure rocks where pressures are seldom otherwise fixed, although it is sensitive to analytical precision and the choice of thermodynamic mixing model for K-feldspar. Moreover, the KJQ barometer is independent of the ratio PH2O/PT. The inferred limiting a(H2O) for the assemblage jadeite–kyanite in the metapelites from Val Savenca is low and varies from 0.2 to 0.6.  相似文献   
58.
The wedge‐shaped Moornambool Metamorphic Complex is bounded by the Coongee Fault to the east and the Moyston Fault to the west. This complex was juxtaposed between stable Delamerian crust to the west and the eastward migrating deformation that occurred in the western Lachlan Fold Belt during the Ordovician and Silurian. The complex comprises Cambrian turbidites and mafic volcanics and is subdivided into a lower greenschist eastern zone and a higher grade amphibolite facies western zone, with sub‐greenschist rocks occurring on either side of the complex. The boundary between the two zones is defined by steeply dipping L‐S tectonites of the Mt Ararat ductile high‐strain zone. Deformation reflects marked structural thickening that produced garnet‐bearing amphibolites followed by exhumation via ductile shearing and brittle faulting. Pressure‐temperature estimates on garnet‐bearing amphibolites in the western zone suggest metamorphic pressures of ~0.7–0.8 GPa and temperatures of ~540–590°C. Metamorphic grade variations suggest that between 15 and 20 km of vertical offset occurs across the east‐dipping Moyston Fault. Bounding fault structures show evidence for early ductile deformation followed by later brittle deformation/reactivation. Ductile deformation within the complex is initially marked by early bedding‐parallel cleavages. Later deformation produced tight to isoclinal D2 folds and steeply dipping ductile high‐strain zones. The S2 foliation is the dominant fabric in the complex and is shallowly west‐dipping to flat‐lying in the western zone and steeply west‐dipping in the eastern zone. Peak metamorphism is pre‐ to syn‐D2. Later ductile deformation reoriented the S2 foliation, produced S3 crenulation cleavages across both zones and localised S4 fabrics. The transition to brittle deformation is defined by the development of east‐ and west‐dipping reverse faults that produce a neutral vergence and not the predominant east‐vergent transport observed throughout the rest of the western Lachlan Fold Belt. Later north‐dipping thrusts overprint these fault structures. The majority of fault transport along ductile and brittle structures occurred prior to the intrusion of the Early Devonian Ararat Granodiorite. Late west‐ and east‐dipping faults represent the final stages of major brittle deformation: these are post plutonism.  相似文献   
59.
通过详细的野外地质调查,在北秦岭双龙-夏馆地区精确圈定出大面积榴闪岩,榴闪岩常以似层状、条带状、豆荚状和透镜状产于秦岭岩群郭庄岩组混合片麻岩内,空间上可划分三个带:南带与松树沟一带的麻粒岩构成一个较宽的高压-超高压变质带,北带则与官坡-双槐树一带的榴辉岩构成一线,而中带向西可能延伸至丹凤大寺沟一带。区内榴闪岩主体受秦岭岩群郭庄岩组的展布形态控制,呈面状遍布于整个郭庄岩组内,而非局限于某一侧或两侧,暗示秦岭岩群可能整体卷入早古生代的俯冲和碰撞作用。野外宏观特征、岩相学及锆石U-Pb年代学研究表明榴闪岩原岩为辉长岩,成岩年龄为654.1±5.6Ma、656.1±6.7Ma,获得峰期高压麻粒岩相变质年龄为472.9±6.0Ma、485.0±33.0Ma,其后分别在455.4±9.0Ma、416.7±1.9Ma和401.1±6.2Ma遭受了多期次退变作用的叠加。结合区域研究成果,初步认为北秦岭高压-超高压基性岩石的原岩至少存在于新元古代中期和晚期,其成岩时代分别与扬子地块北缘新元古代中、晚期的镁铁-超镁铁质岩床群一致,并具有相似的地球化学特征,而两者是否为同一大地构造背景下的同期侵位的产物,尚待进一步研究。  相似文献   
60.
Within the Tethyan realm, data for the subduction history of the Permo–Triassic Tethys in the form of accretionary complexes are scarce, coming mainly from northwest Turkey and Tibet. Herein we present field geological, petrological and geochronological data on a Triassic accretionary complex, the A?vanis metamorphic rocks, from northeast Turkey. The A?vanis metamorphic rocks form a SSE–NNW trending lozenge‐shaped horst, ~20 km long and ~6 km across, bounded by the strands of the active North Anatolian Fault close to the collision zone between the Eastern Pontides and the Menderes–Taurus Block. The rocks consist mainly of greenschist‐ to epidote‐amphibolite‐facies metabasite, phyllite, marble and minor metachert and serpentinite, interpreted as a metamorphic accretionary complex based on the oceanic rock types and ocean island basaltic, mid‐ocean ridge basaltic and island‐arc tholeiitic affinities of the metabasites. This rock assemblage was intruded by stocks and dikes of Early Eocene quartz diorite, leucogranodiorite and dacite porphyry. Metamorphic conditions are estimated to be 470–540°C and ~0.60–0.90 GPa. Stepwise 40Ar/39Ar dating of phengite–muscovite separates sampled outside the contact metamorphic aureoles yielded steadily increasing age spectra with the highest incremental stage corresponding to age values ranging from ~180 to 209 Ma, suggesting that the metamorphism occurred at ≥ 209 Ma. Thus, the A?vanis metamorphic rocks represent the vestiges of the Late Triassic or slightly older subduction in northeast Turkey. Estimated P–T conditions indicate higher temperatures than those predicted by steady state thermal models for average subduction zones, and can best be accounted for by a hot subduction zone, similar to the present‐day Cascadia. Contact metamorphic mineral assemblages around an Early Eocene quartz diorite stock, on the other hand, suggest that the present‐day erosion level was at depths of ~14 km during the Early Eocene, indicative of reburial of the metamorphic rocks. Partial disturbance of white‐mica Ar–Ar age spectra was probably caused by the reburial coupled with heat input by igneous activity, which is probably related to thrusting due to the continental collision between Eastern Pontides and the Menderes–Taurus Block.  相似文献   
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